The researchers state that fluoride anions are an important target in supramolecular chemistry due to the importance of. Supramolecular gels that change their state or structure in response to anion stimuli have been highlighted. Static molecular recognition is likened to the interaction between a key and a keyhole. Our aim is to provide researchers with a forum to present work at the forefront of supramolecular chemistry, while stimulating the development of exciting. Anion receptor catalysis and molecular recognition and transformation of nucleotides supramolecular chemistry of anions is a valuable professional resource for organic and inorganic chemists, analytical chemists, biotechnologists, pharmaceutical scientists, and environmental chemists. Nov 27, 2015 europe pmc is an archive of life sciences journal literature. The study of the complexation of anions, from its beginnings in the late 1960s and 1970s, has moved on from being an area solely of academic interest to a fundamental pillar of supramolecular chemistry with applications in many areas. Over recent years we have seen the development of a plethora of anion sensors, anion responsive materials, organocatalytic processes involving anion complexation.
Article views are the countercompliant sum of full text article downloads since november 2008 both pdf and html across all institutions and individuals. Whitea aresearch school of chemistry, australian national university 7 sullivans creek road, acton, 2601, act, australia email. Supramolecular chemistry is a must for both students new to the field and for experienced researchers wanting to explore the origins and wider context of their work about the author jonathan w. Synthesis and anion recognition hiromitsu maeda acyclic oligopyrrolic anion receptors jeffery t. Supramolecular catalysis of phosphoryl anion transfer processes 421 mir wais hosseini, universite louis pasteur, strasbourg, france 11. Supramolecular chemistryconcepts and applications ajay kumar manna ramananda college, department of chemistry, bishnupur, bankura, west bengal, 722122, india abstract. Important concepts that have been demonstrated by supramolecular chemistry include molecular selfassembly, folding, molecular. A supramolecular photonic device porphyrins and tetrapyrrole macrocycles 2. The recognition of anions in water remains a key challenge in modern supramolecular chemistry, and is essential if proposed applications in biological, medical, and environmental arenas that typically require aqueous conditions are to be achieved. Kindly follow the instructions to unlock the download link. May 21, 2015 applications of supramolecular anion recognition. Molecular recognition can be subdivided into static molecular recognition and dynamic molecular recognition.
Anion sensing by discrete molecular receptors relies on the fact that the recognition of a given anion by a receptor can induce a response, be it an optical color change or fluorescence, an electrochemical, or a solgel transition, that can be used to monitor the presence and in some cases the concentration of an anionic guest. Journal of the american chemical society 2017, 9 1, 5558. Anion recognition in supramolecular chemistry philip a. Sometime download links are not visible on mobile devices, so if you face this issue, kindly do visit this page via laptopdesktop computer. Molecular recognition supramolecular chemistry wiley.
The application of anion transporters to the potential future treatment of disease is d supramolecular chemistry anniversary. The field of anion coordination chemistry has received more and more attention in recent years. Supramolecular chemistrygeneral principles and selected. Applications of supramolecular anion recognition eprints soton. Free supramolecular chemistry books download ebooks online. Synthesis and anion recognition hiromitsu maeda acyclic oligopyrrolic anion. In supramolecular chemistry noncovalent interactions occur between molecular building blocks, which by molecular recognition and selfassembly form functional supramolecular entities. Supramolecular chemistry refers to the domain of chemistry beyond that of molecules and focuses on the chemical systems made up of a discrete number of assembled molecular subunits or components. The synthesis of ph dependant macrocycles for switchable.
This thesis is concerned with the synthesis of a range of ph switchable macrocycles and their ability to bind anions. Supramolecular chemistry is the science that bridges the gap between the world of molecules and nanotechnology. His research interests cover several aspects of supramolecular chemistry including metal template reactions, molecular switches of fluorescence, anion recognition and sensing, and molecular machines based on ion translocation. Linear supramolecular pseudorotaxane polymers were formed with reversible chain extension in solution by selfassembly of two complimentary homoditopic molecules with secondary ammonium ion and dibenzo24crown8 moieties. The wholly complexed selfassembling dendrimers were evidenced by 1h nmr spectroscopy and mass spectrometry. Fulltext downloads displays the total number of times this works files e. Supramolecular chemistry of anions supramolecular chemistry. Boron complexes of 1,3dipyrrolyl1,3propanediones with arylsubstituents, as a new class of acyclic anion receptors, have shown efficient binding due to the interacting och units and, in the case of the derivative with long aliphatic chains, afforded the emissive supramolecular organogels using stacking of core. Anion sensing by discrete molecular receptors relies on the fact that the recognition of a given anion by a receptor can induce a response, be it an optical color change or fluorescence, an electrochemical, or a solgel transition, that can be used to monitor the presence and in. The cell internalization of designed oligoarginine peptides equipped with six glutamic acid residues and an anionic pyranine at the nterminus is triggered upon addition of a supramolecular host.
Supramolecular chemistry of nanomaterials pdf 36p this note covers the following topics. Polymer bound supramolecular assemblies for anion sensing. Supramolecular chemistry concepts and applications ajay kumar manna ramananda college, department of chemistry, bishnupur, bankura, west bengal, 722122, india abstract. It is one of todays fastest growing disciplines, crossing a range of subjects from biological chemistry to materials science. A large number of articles, from the initial anion recognition to various applications, have been published in the past few decades. Covalent polymers containing discrete heterocyclic anion receptors. Anion transport and supramolecular medicinal chemistry. Anion recognition in supramolecular chemistry topics in. Arylsubstituted c3bridged oligopyrroles as anion receptors.
This chapter discusses supramolecular chemistry of environmentally relevant anions. Only a few examples exist of such supramolecular gels, the structures and properties of which can be controlled and modulated by interactions with anions. The count includes downloads for all files if a work has more than one. Anion recognition in supramolecular chemistry topics in heterocyclic chemistry 2010th edition by philip a. In 2010, he received the izattchristensen award in macrocyclic chemistry. Europe pmc is an archive of life sciences journal literature. The ultimate goal of the studies on the basic chemical aspects of anion receptor design of functional phindependent systems is to target selective binding of anions of environmental significance. Supramolecular chemistry is an uptodate, integrated textbook that tells the newcomer to the field everything. Applications of supramolecular anion recognition chemical.
Free download supramolecular chemistry 2e chemistry. Introduction the award of nobel prize to charles j pedersen, donald j cram and jeanmarie lehn in 1987 marked the emergence of a new branch of chemistry, namely supramolecular chemistry. Davis anion binding and transport by prodigiosin and its analogs. It can be described as the study of systems which contain more than one molecule, and it aims to understand the structure, function, and properties of these assemblies. Supramolecular chemistry is the domain of chemistry concerning chemical systems composed of a discrete number of molecules. Article page 3 molecular recognition and supramolecular.
Researchers discuss applications of supramolecular anion recognitions. Anion recognition as a supramolecular switch of cell internalization. Jul 25, 2018 fulltext downloads displays the total number of times this works files e. Recognition of ammonium ions and related substrates. This host binds specifically to the pyranine moiety, enabling the complex to traverse the cell membrane. Written by a group comprising pioneering researchers from the united states and europe, supramolecular chemistry of anions covers all theoretical and practical aspects of anion complexation, from. Chapter 1 provides an introduction to anion recogntion within supramolecular chemistry and introduces switchable anion recognition and potential application of such. Supramolecular chemistry at surfaces charged anion and cation and small molecule receptor chemistry developments in theoretical and practical aspects of supramolecular chemistry. In the second part those will be illustrated by simple examples from our laboratories. Therefore, i hope that chinese scientists are eager to face the major challenge of chemistry and to do more creative work for advancing chemistry and promoting technology transfer. The strength of the forces responsible for spatial organization of the system range from weak intermolecular forces, electrostatic charge, or hydrogen bonding to strong covalent bonding, provided that the electronic coupling strength remains small relative to the energy. Lecture notes on supramolecular chemistry download book.
Responsive supramolecular gels, chemistry a european. Supramolecular chemistry of nanomaterials department of chemistry imperial college of science, technology and medicine r. An ultrasensitive and selective turn off fluorescent sensor with simple operation for the determination of trace copper ii ions in water and various beverage samples. Supramolecular chemistry of environmentally relevant anions. Anion recognition as a supramolecular switch of cell. Alireza azhdari tehrani, sedigheh abedi, and ali morsali. Supramolecular chemistry is chemistry beyond the molecule the chemistry of molecular assemblies and intermolecular bonds. Free download supramolecular chemistry 2nd edition in pdf. Applications of supramolecular anion recognition request pdf. Supramolecular chemistry is the science that bridges the gap between the world of. Anion recognition in supramolecular chemistry springerlink. Supramolecular chemistry may thus be expected to have a strong impact on materials science via the manipulation of the noncovalent forces that hold the constituents together, leading up to the design of smart, functional supramolecular materials and the control of their buildup and of their properties by selfassembly from suitable units. Nov 27, 2015 the recognition of anions in water remains a key challenge in modern supramolecular chemistry, and is essential if proposed applications in biological, medical, and environmental arenas that typically require aqueous conditions are to be achieved. Unlimited viewing of the articlechapter pdf and any associated supplements and figures.
1377 950 528 1212 854 793 610 533 933 519 511 1086 926 560 903 829 257 60 832 431 496 521 623 828 601 697 1369 1445 1476 1100 1555 154 1009 497 1367 799 1226 754 726 779 1476 620